VALVOLINE OIL CO SUBSIDIARY OF ASHLAND OIL INC. -- 20-9523 FREON 22 -- 6830-00-935-9896 
=====================  Product Identification  =====================

Product ID:20-9523 FREON 22
MSDS Date:05/31/1989
FSC:6830
NIIN:00-935-9896
=== Responsible Party ===
Company Name:VALVOLINE OIL CO SUBSIDIARY OF ASHLAND OIL INC.
Address:200 E MAIN ST
Box:14000
City:LEXINGTON
State:KY
ZIP:40512
Country:US
Info Phone Num:606-264-7000/7616;FAX 601-429-0537
Emergency Phone Num:800-ASHLAND/800-274-5263
CAGE:72527
=== Contractor Identification ===
Company Name:BALKAMP INC
Address:2601 S HOLT ROAD
Box:City:INDIANAPOLIS
State:IN
ZIP:46241
Country:US
Phone:317-244-7241
CAGE:70842
Company Name:NAPA, A DIVISION OF LINCOLN AUTOMOTIVE
Address:ONE LINCOLN WAY
Box:City:ST. LOUIS
State:MO
ZIP:63120-1578
Country:US
Phone:414-255-5520
CAGE:050Q3
Company Name:VALVOLINE OIL CO
Address:3499 BLAZER PKY
Box:14000
City:LEXINGTON
State:KY
ZIP:40512
Country:US
Phone:606-357-7206 / 800-274-5263
CAGE:72527

=============  Composition/Information on Ingredients  =============

Ingred Name:CHLORODIFLUOROMETHANE (SARA 313) (CERCLA)
CAS:75-45-6
RTECS #:PA6390000
Fraction by Wt: 85-100%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM; 9596
Ozone Depleting Chemical:2

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:TLV:1000 PPM.
Routes of Entry: Inhalation:YES  Skin:NO  Ingestion:NO
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:EYE:CAN CAUSE SEVERE
    IRRIT,REDNESS,TEARING,BLURRED VISION.SKIN:PROL/REP CONTACT CAN
    CAUSE MODERATE IRRIT,DEFATTING,DERM.BREATH:EXCESSIVE VAP INHAL CAN
    CAUSE NASAL/RESP IRRIT,CNS EFFECTS INCLUDING DIZZ
    ,WEAK,FTG,NAU,HEAD,POSSIBLE UNCONSC,EVEN DEATH.INGEST:CAN CAUSE
    GASTROINTESTINAL IRRIT,NAU,VOMIT,DIARRHEA.
Effects of Overexposure:SEVERE EYE IRRIT,REDNESS,TEARING,BLURRED
    VISION. MODERATE SKIN IRRIT,DEFATTING,DERM. NASAL/RESPIRATORY
    IRRIT,CNS EFFECTS-DIZZINESS,WEAKNESS,FTG,NAU,HEADACHE,POSSIBLE
    UNCONSC,DEATH. GASTROINTESTINAL IR RIT,NAU,VOMIT,DIARRHEA.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

=======================  First Aid Measures  =======================

First Aid:SKIN:THOROUGHLY WASH W/SOAP/WATER.REMOVE CONTAMIN
    CLOTH.EYE:FLUSH W/LG AMTS OF WATER LIFTING UPPER/LOWER LIDS
    OCCASIONALLY.GET MED ATTN.INGEST:DO NOT INDUCE VOMIT.IMMED DRINK 2
    GLASSES OF WATER.NEVER  GIVE ANYTHING BY MOUTH IF UNCONSC.CALL
    DR/TRANSP TO EMERG FACILITY.INHAL:REMOVE TO FRESH AIR.BREATH DIFFI
    ADMIN OXY;BREATH STOP GIVE ART RESP.KEEP WARM/QUIET.GET MED ATTN.DO
    NOT GIVE STIMULANTS.(SUPP)

=====================  Fire Fighting Measures  =====================

Autoignition Temp:Autoignition Temp Text:NP
Lower Limits:NA
Upper Limits:NA
Extinguishing Media:WATER FOG.
Fire Fighting Procedures:WEAR SCBA W/FULL FACEPIECE OPERATED IN
    POSITIVE PRESSURE DEMAND MODE WHEN FIGHTING FIRES.
Unusual Fire/Explosion Hazard:NEVER USE WELD/CUT TORCH ON/NEAR DR(EVEN
    EMPTY)-PROD(EVEN JUST RESIDUE)CAN IGN EXPLOSIVELY.

==================  Accidental Release Measures  ==================

Spill Release Procedures:SM:ABSORB ON PAPER/VERMI/FLOOR ABSORB/OTHER
    ABSORB MATL.LG:PERSON NOT WEARING PROT EQPMT SHOULD BE EXCLUDED
    FROM AREA TIL CLEANUP COMPLETED.STOP SPILL/DIKE TO PREVENT
    SPREADING.PUMP TO SALVAGE TK.REMA INING LIQ MAYBE TAKEN UP ON
    SAND/CLAY/EARTH(SUPPL)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:CNTNR OF THIS MATL MAY BE HAZ WHEN
    EMPTIED SINCE THEY RETAIN PROD RESIDUE(VAP,LIQ,SOLID).ALL HAZ
    PRECAUTION GIVEN IN MSDS MUST BE OBSERVED.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:WORKPLACE EXPO PROD/COMPONENT LIMITS
    EXCEEDED,NIOSH/MSHA APPROVE AIR SUPPLIED RESP ADVISED IN ABSENCE OF
    PROPER ENVIRO CNTRL.OSHA REGS PERMIT OTHER NIOSH/MSHA RESP UNDER
    SPEC CONDITIONS.(SEE SAF EQPMT  SUPPLIER).IMPLEMENT ENGIN/ADMIN
    CNTRL.
Ventilation:PROIVDE SUFFICIENT MECHANICAL(GEN &/OR LOC
    EXHAUST)VENTILATION TO MAINTAIN EXPO BELOW TLVS.
Protective Gloves:RESISTANT GLOVES:NITRILE RUBBER.
Eye Protection:CHEM SPLASH GOGG,OTHER OSHA TYPE GLASSES
Other Protective Equipment:NORMAL WORK CLOHTING COVERING ARMS/LEGS.
Work Hygienic Practices:WASH CONTAMIN CLOTH BEF REUSE.
Supplemental Safety and Health
1STAID:EPINEPHRINE OR EPHEDRINE AMY ADVERSELY AFFECT THE HEART W/FATAL
    RESULTS. SPILL:OTHER ABSORB MATL;SHOVEL INTO CNTNRS.PREVENT RUNOFFS
    INTO SEWER/ETC ENTRY;IF SO NOTIFY AUTHORITIES

==================  Physical/Chemical Properties  ==================

HCC:G3
Boiling Pt:B.P. Text:-41F,-41C
Melt/Freeze Pt:M.P/F.P Text:NP
Decomp Temp:Decomp Text:NP
Vapor Pres:7805MM@77F
Vapor Density:7.0
Spec Gravity:1.190 @77F
pH:NP
Viscosity:NP
Evaporation Rate & Reference:FASTER THAN ETHER.
Solubility in Water:NP
Appearance and Odor:CLEAR, COLORLESS LIQUID, HOMOG SOLN.
Percent Volatiles by Volume:100
Corrosion Rate:NP

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT W/STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:MAY FORM TOXIC MATLS,CO2, CO, HYDROGEN
    CHLORIDE, PHOSGENE, HYDROGEN FLUORIDE, VARIOUS HYDROCARBONS, ETC.

====================  Disposal Considerations  ====================

Waste Disposal Methods:SM:ALLOW VOLATILE PORTION TO EVAPORATE IN
    HOOD.ALLOW SUFFICIENT TIME FOR VAP TO COMPLETELY CLEAR HOOD
    DUCTWORK.DISPO REMAIN MATL IAW APPLICABLE REGS.LG:VENTILATE AREA OF
    SPILL.ALLOW MATL TO EVAPORATE.

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