ALLIED-SIGNAL INC, ENGINEERED MATERIALS SECTOR -- GENETRON 11 (TRICHLOROFLUOROMETHANE) -- 6830-00-281-3036 
=====================  Product Identification  =====================

Product ID:GENETRON 11 (TRICHLOROFLUOROMETHANE)
MSDS Date:02/01/1993
FSC:6830
NIIN:00-281-3036
=== Responsible Party ===
Company Name:ALLIED-SIGNAL INC, ENGINEERED MATERIALS SECTOR
Box:1139R
City:MORRISTOWN
State:NJ
ZIP:07962-1139
Country:US
Info Phone Num:800-522-8001
Emergency Phone Num:800-522-8001
CAGE:1L164
=== Contractor Identification ===
Company Name:ALLIED-SIGNAL INC
Box:2332R
City:MORRISTOWN
State:NJ
ZIP:07962-2332
Country:US
Phone:201-455-4414
CAGE:1L164

=============  Composition/Information on Ingredients  =============

Ingred Name:TRICHLOROFLUOROMETHANE  (CFC-11) (SARA 313) (CERCLA)
CAS:75-69-4
RTECS #:PB6125000
Fraction by Wt: 100%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1000 PPM
ACGIH TLV:C 1000 PPM; 9596
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ozone Depleting Chemical:1

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:LD50 (MOUSE): 1743MG/KG.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:INHAL:VAP SLIGHTLY IRRIT LUNG.BREATH
    CONC APPROACHING 10% IN AIR CAUSE DIZZ,DIFFI
    BREATH,DROWSINESS,POSSIBLY NARCOSIS.INGEST:UPSET,IRRIT GI
    TRACT.ESTIMATED TO HAVE MODERATE TOXICITY.SAME SYMPTOMS AS I
    NHAL.SKIN:EXCESSIVE CONTACT MAY CAUSE IRRIT(DEFAT ACTION),POSSIBLE
    FROSTBITE(REFRIG EFFECT OF EVAPORATION).EYE:LIQ(SUPP)
Explanation of Carcinogenicity:PER MSDS:A NCL-SPONSORED BIOASSAY ON
    CARCINOGENICITY (RATS) GAVE NEGATIVE RESULTS.
Effects of Overexposure:SLIGHTLY IRRIT LUNG. DIZZINESS, DIFFICULT
    BREATH, DROWSINESS, NARCOSIS. UPSET, IRRIT GI TRACT. SKIN IRRIT,
    FROSTBITE. YE:IRRIT.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

=======================  First Aid Measures  =======================

First Aid:INHAL:IMMED REMOVE TO FRESH AIR.STOP BREATH GIVE
    MOUTH-TO-MOUTH RESUSC.GIVE OXY BY QUAL PERSON IF AVAILABLE.CALL
    DR.DON'T GIVE ADRENALIN(EPINEPHRINE).EYE:RPOMPTLY FLUSH W/LG AMTS
    OF WATER.LIFT EYELIDS .IRRIT CONSULT DR.SKIN:PROMPTLY WASH
    W/SOAP/WATER THEN FLUSH W/WATER TIL CHEM REMOVED.REMOVE CONTAMIN
    CLOTH.INGEST:UNLIKELY EXPO ROUTE.NOT EXPECTED TO BE HAZ.DO NOT
    INDUCE VOMIT UNLESS INSTRUCTED(SUP)

=====================  Fire Fighting Measures  =====================

Flash Point:NON-FLAMMABLE
Autoignition Temp:Autoignition Temp Text:NA
Lower Limits:NA
Upper Limits:NA
Extinguishing Media:ANY STD AGENT.SELECT ONE MOST SUITABLE FOR TYPE OF
    FIRE.MATL ITSELF NOT FLAMMABLE.
Fire Fighting Procedures:WEAR NIOSH-APPROVED SCBA FOR PROT AGAINST
    SUFFO/POSSIBLE TOXIC DECOMPO PROD.COOL FIRE-EXPO CNTNR/KEEP SPILL
    AWAY FROM FIRE/HEAT/KNOCK DOWN VAP W/WATER SPRAY.
Unusual Fire/Explosion Hazard:NOT COMBUST ITSELF CONTACT W/CERTAIN
    METALS PRODUCES RAPID EXO RX/POT EXPLO COMBINATINS.

==================  Accidental Release Measures  ==================

Spill Release Procedures:EVACUATE UNPROT PEOPLE.PROT PEOPLE
    W/SELFCONTAIN AIR SUPLLY RMOEV FLAME/SHUT OFF LEAK/PROVIDE
    VENTI.ABSORB LIQ W/COMMERCIAL ABSORBENT/SHOVEL INTO METAL
    DRM/CLS.DIKE LG SPILLS W/INERT MATL/COMM ABSORBE NT/PUMP INTO
    DR.PUMP NOT OVERHEAT.KEEP OUT OF SEWR
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:AVOID BREATH VAP/LIQ CONTACT
    W/EYE/SKIN/CLOTH.TANK-CLEAN PEOPLE SHOULD USE ONLY FORMAL TK ENTRY
    PROCEDURE BASED ON RECOGN SAF PRINCIPLES.
Other Precautions:FOLLOW PRECAUT ON LABEL.STORAGE AREAS CLEAN WELL
    VENTI AWAY FROM HEAT/DIR SUNLIGHT/LOW FIRE RISK.PROT CNTNR FRM PHY
    DMG/KEEP CLSD.SPEC ATTN GIVEN TO VENTI OF LOWLYING AREA/SM ENCLSR
    WHERE MATL STORE/U SED-AVOID ASHPYXIATION.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:NONE REQUIRED FOR NORMALLY-VENITED WORK
    SITUATIONS.FOR ACCIDENTAL OR NON-VENTI SITUATIONS WHERE VAP CONC
    MAY BE HIGH, USE SELF-CONTAINED BREATHING APPARATUS OR SUPPLIED-AIR
    RESP, NIOSH-APPROVED.
Ventilation:VENTI SHOULD BE ADEQU TO MEET TLV REQMTS/MIN EXPO TO
    VAP.LOC EXHAU:@FILL ZONE,WHERE LEAKAGE PROBABLE.MECH:ADEQ STORAGE.
Protective Gloves:PVA, NEOPRENE IMPERVIOUS GLOVES.
Eye Protection:SAFETY GOGG,FACE SHIELD.
Other Protective Equipment:DO NOT WEAR CONTACT LENSES.PROTECTIVE
    IMPERVIOUS CLOTH(PREFER PVA,NEOPRENE).EYEWASH STATIONS,QUICK DRENCH
    SHOWER FACILI.
Work Hygienic Practices:WASH CONTAMIN BEF REUSE.
Supplemental Safety and Health
HEALTH HAZ:CONTACT IRRIT.VAP ESTIMATED TO BE MILDLY IRRIT. 1STAID:TO DO
    SO BY PHYSICIAN.

==================  Physical/Chemical Properties  ==================

HCC:N1
Boiling Pt:B.P. Text:74.8F,23.8C
Melt/Freeze Pt:M.P/F.P Text:-168F,-111C
Decomp Temp:Decomp Text:NP
Vapor Pres:13.4 PSIA
Vapor Density:5.06 @30C
Spec Gravity:1.49 @21.1C LIQ
pH:N/DETE
Viscosity:NP
Evaporation Rate & Reference:0.4, ETHER=1
Solubility in Water:0.11 @25C SLIGHT
Appearance and Odor:LIQUID, COLORLESS, WITH FAINT ETHER-LIKE ODOR.
Percent Volatiles by Volume:100
Corrosion Rate:NP

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
AL/AL POWDER,GRANULAR BA,LITHIUM SHAVINGS,CHEM ACTIVE
    METALS(NA,K,CA,POWDERED MG,ZN).
Stability Condition to Avoid:FLAMES, LIGHTED CIGARETTES, HOT SPOTS,
    WELDING (DECOMPOSES, LIBERATING HAZARDOUS GASES).
Hazardous Decomposition Products:HALOGENS, HALOGEN ACIDS, & POSSIBLY
    CARBONYL HALIDES SUCH AS PHOSGENE.

====================  Disposal Considerations  ====================

Waste Disposal Methods:RQ:5000.PROD USED AS SOLVNT SUBJ TO
    FED/STATE/LOC REGS WHEN DISPO(EPA SPENT HALOGENATED
    SOLVNT-F001,F002).UNUSED U121.USERS SHOULD REVIEW OPERATIONS IN
    TERMS OF APPLICABLE FED/STATE/LOC LAW/REG.CONSUL T APPROP REG
    AGENCIES BEF DISCHAR/DISPO.DESTROY O3

 Disclaimer (provided with this information by the compiling agencies):
 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.